Galeri MolScript: Mekanisme Reaksi yang Ditulis sebagai Teks
Setiap mekanisme di bawah ini adalah beberapa baris MolScript dan gambar yang dibuat MolDraw darinya. Ini adalah skrip yang sama yang diuji MolDraw pada setiap perubahan: masing-masing harus tergambar dengan setiap panah lengkung ditempatkan sesuai aturan menggambar, dan panahnya harus menghasilkan, elektron demi elektron, produk yang ditulis sesudahnya. Suatu mekanisme hanya muncul di sini jika lulus uji.
Salin skrip mana pun ke tab MolScript di panel Templates di MolDraw, atau minta mekanisme kepada asisten AI, lalu sunting dari sana.
SN2
title: SN2 of bromomethane [OH-:1] "hydroxide" + [CH3:2][Br:3] "bromomethane" ->[SN2][acetone] CO "methanol" + [Br-] move :1 -> 1..2 move 2-3 -> 3
SN1
title: SN1 of tert-butyl bromide C[C:1](C)(C)[Br:2] ->[slow] C[C+:3](C)C + [Br-] move 1-2 -> 2 -> C[C+:4](C)C + [OH2:5] move :5 -> 5..4 ->[fast] CC(C)(C)[OH2+]
E2
title: E2 elimination [OH-:1] + [H:4][CH2:2][CH:3](C)[Br:5] ->[E2] C=CC + O + [Br-] move :1 -> 1..4; 4-2 -> 2-3; 3-5 -> 5
Sianohidrin
title: Cyanide addition to a carbonyl [C-:1]#N + C[CH:2]=[O:3] -> CC([O-])C#N move :1 -> 1..2 move 2-3 -> 3
Reduksi hidrida
title: NaBH4 reduction of acetone [H:1][BH3-:2] + C[C:3](C)=[O:4] ->[H⁻ transfer] CC([O-])C move 1-2 -> 1..3 move 3-4 -> 4
Hidrolisis ester (tahap adisi)
[OH-:1] + C[C:2](=[O:3])OC ->[addition] CC([O-])(O)OC move :1 -> 1..2 move 2-3 -> 3
Runtuhnya zat antara tetrahedral
C[C:1]([O-:2])(O)[O:3]C ->[elimination] CC(=O)O + [O-]C move :2 -> 2-1 move 1-3 -> 3
Adisi aldol
title: Aldol addition [CH2-:1]C(C)=O "enolate" + C[CH:2]=[O:3] "acetaldehyde" -> CC([O-])CC(C)=O move :1 -> 1..2 move 2-3 -> 3
Adisi Michael
title: Michael addition [CH2-:1]C(C)=O + [CH2:2]=[CH:3][C:4](C)=[O:5] ->[1,4-addition] CC(=O)CCC=C(C)[O-] move :1 -> 1..2; 2-3 -> 3-4; 4-5 -> 5
Resonansi enolat
[CH2-:1][C:2](C)=[O:3] <-> C=C(C)[O-] move :1 -> 1-2 move 2-3 -> 3
Resonansi nitro
C[N+:1](=[O:2])[O-:3] <-> C[N+]([O-])=O move :3 -> 3-1 move 1-2 -> 2
Resonansi kation alil
[CH2:1]=[CH:2][CH2+:3] <-> [CH2+]C=C move 1-2 -> 2-3
Protonasi karbonil
[O:1]=C(C)C + [H:3][OH2+:4] ->[H⁺ transfer] [OH+]=C(C)C + O move :1 -> 1..3 move 3-4 -> 4
Tahap hemiasetal
C[CH:1]=[OH+:2] + [OH:3]C ->[addition] CC(O)[OH+]C move :3 -> 3..1 move 1-2 -> 2
Pembukaan epoksida
[OH-:1] + C[CH:2]1[O:3]C1 ->[SN2] CC(O)C[O-] move :1 -> 1..2 move 2-3 -> 3
Brominasi alkena
title: Bromination of ethene [CH2:1]=[CH2:2] + [Br:3][Br:4] -> C1C[Br+]1 + [Br-] move 1-2 -> 3; :3 -> 3..2 move 3-4 -> 4
Serangan Friedel-Crafts
[CH:1]1=[CH:2]C=CC=C1 + C[C+:3]=O ->[SEAr] CC(=O)C1C=CC=C[CH+]1 move 1-2 -> 2..3
Deprotonasi ion arenium
CC(=O)[C:1]1([H:2])C=CC=C[CH+:3]1 + [Cl-:4] ->[−H⁺] CC(=O)c1ccccc1 + Cl move :4 -> 4..2; 2-1 -> 1-3
Diels-Alder
title: Diels–Alder [CH2:1]=[CH:2][CH:3]=[CH2:4] + [CH2:5]=[CH2:6] ->[Δ] C1CC=CCC1 move 1-2 -> 2-3; 3-4 -> 4..5; 5-6 -> 6..1
Homolisis bromin
[Br:1][Br:2] ->[hν] [Br] + [Br] move 1-2 ~> 1; 1-2 ~> 2
Adisi radikal
title: Radical addition of Br• to propene [Br:1] + [CH2:2]=[CH:3]C -> BrC[CH]C move 1 ~> 1..2 move 2-3 ~> 1..2 move 2-3 ~> 3
Resonansi karboksilat
C[C:1](=[O:2])[O-:3] <-> CC([O-])=O move :3 -> 3-1 move 1-2 -> 2
SN2 melalui keadaan transisinya
title: SN2 through its transition state
per-row: 5
[OH-:1] + [CH3:2][Br:3] {δ+=2 δ-=3} -> [OH]~C([H])([H])([H])~[Br] {ts} -> CO + [Br-]
move :1 -> 1..2; 2-3 -> 3
Adisi nukleofilik dengan gugus R
title: Nucleophile adds to a ketone [Nu-:1] + [R1][C:2](=[O:3])[R2] -> [Nu]C([R1])([R2])[O-] move :1 -> 1..2; 2-3 -> 3
E2 dengan hidrogen bernama
title: E2 elimination (hN names the hydrogen) let base = [OH-:1] "hydroxide" $base + [CH3:2][CH:3](C)[Br:5] ->[E2] C=CC + O + [Br-] move :1 -> 1..h2; h2-2 -> 2-3; 3-5 -> 5
Asilasi Friedel-Crafts dengan struktur reagen
title: Friedel–Crafts acylation
c1ccccc1 ->[{CC(=O)Cl}][AlCl3] CC(=O)c1ccccc1 + Cl
Siklus katalitik Suzuki
title: Suzuki coupling: catalytic cycle layout: cycle [Pd] "Pd(0)" ->[oxidative addition][+ ArBr] Br[Pd][Ar] ->[transmetalation][+ PhB(OH)2] [Ph][Pd][Ar] ->[reductive elimination][− Ar–Ph] [Pd]
Pembentukan imina: adisi amina
title: Imine formation, step 1 C[CH:1]=[O:2] + [NH2:3]C ->[addition] CC([O-])[NH2+]C move :3 -> 3..1; 1-2 -> 2
Pembentukan oksokarbenium (asetal)
title: Acetal formation: loss of water C[CH:1]([O:2]C)[OH2+:3] -> C[CH]=[O+]C + O move :2 -> 2-1; 1-3 -> 3
Deprotonasi E1
title: E1: water removes a proton C[C+:1](C)[CH3:2] + [OH2:3] -> C=C(C)C + [OH3+] move :3 -> 3..h2; h2-2 -> 2-1
Adisi kondensasi Claisen
title: Claisen condensation: enolate addition [CH2-:1]C(=O)OC + C[C:2](=[O:3])OC -> COC(=O)CC(C)([O-])OC move :1 -> 1..2; 2-3 -> 3
Pembentukan halohidrin
title: Water opens a bromonium ion [CH2:2]1[CH2:3][Br+:1]1 + [OH2:4] -> [OH2+]CCBr move :4 -> 4..2; 2-1 -> 1
Propagasi klorinasi radikal
title: Chlorination of methane: propagation [Cl:1] + [H:2][CH3:3] ->[hν] Cl + [CH3] move 1 ~> 1..2; 2-3 ~> 1..2; 2-3 ~> 3
Penggabungan radikal metil
title: Radical termination [CH3:1] + [CH3:2] -> CC move 1 ~> 1..2; 2 ~> 1..2
Deprotonasi asam karboksilat
title: Hydroxide deprotonates acetic acid [OH-:1] + CC(=O)[OH:2] -> CC(=O)[O-] + O move :1 -> 1..h2; h2-2 -> 2
Resonansi amida
C[C:1](=[O:2])[NH2:3] <-> CC([O-])=[NH2+] move :3 -> 3-1; 1-2 -> 2
SN1 tanpa nomor peta
title: SN1 with element ends, numbered, snake rows number: both wrap: snake per-row: 3 CC(C)(C)Br ->[slow] C[C+](C)C + [Br-] move C-Br -> Br -> C[C+](C)C + O move :O -> O..C+ ->[fast] CC(C)(C)[OH2+]
SN2 yang disorot
title: SN2 with the reacting atoms highlighted
[OH-:1] {highlight=1:blue} + [CH3:2][Br:3] {highlight=2/2-3:red} -> CO + [Br-]
move :1 -> 1..2; 2-3 -> 3
Siklus Pd dengan bilangan oksidasi
title: Cross-coupling cycle with oxidation states
layout: cycle
[Pd:1] {ox=1:0} ->[oxidative addition][+ ArX] [X][Pd:2][Ar] {ox=2:II}
->[transmetalation][+ R–M] [R][Pd:3][Ar] {ox=3:II}
->[reductive elimination][− Ar–R] [Pd:1]
Adisi Grignard (pasangan ion)
title: Grignard addition to a ketone [CH3:1][Mg:2]Br + C[C:3](C)=[O:4] -> CC(C)(C)[O-] + [Mg+]Br move 1-2 -> 1..3; 3-4 -> 4
Protonasi alkoksida
title: Work-up: the alkoxide is protonated CC(C)(C)[O-:1] + [H:2][OH2+:3] -> CC(C)(C)O + O move :1 -> 1..2; 2-3 -> 3
